Study on Catalysis of Cu-Fe Metal Composite Oxides to Thermal Decomposition Behavior of Bluestone

نویسندگان

  • Hui Wei Liao Material Science and Engineering College, Southwest University of Science and Technology, Mianyang Sichuan, CHINA
  • Lan Mu Material Science and Engineering College, Southwest University of Science and Technology, Mianyang Sichuan, CHINA
  • Min Zhen Material Science and Engineering College, Southwest University of Science and Technology, Mianyang Sichuan, CHINA
  • Yan Yan Meng Material Science and Engineering College, Southwest University of Science and Technology, Mianyang Sichuan, CHINA
چکیده مقاله:

Nano-CuFe2O4 catalysts with different Cu/Fe molar ratios (CunFemO(n+1.5m)) were prepared by hydrothermal method. The thermal decomposition performance of CunFemO(n+1.5m) on CuSO4 were determined with TG-DSC method to evaluate its catalytic activity and the roasted product was characterized by XRD. The results showed that CunFemO(n+1.5m) had superior catalytic properties and efficiency to CuSO4 crystals in 1:1 Cu/Fe molar ratios and 4% CunFemO(n+1.5m) (in mass) contained. Under these conditions, the high and low temperature decomposition peaks of CuSO4 were overlapped. The temperature and heat of decomposition were decreased by 29.5 °C and 112.1 J/g, respectively. The results were also confirmed by roasting experiments of CuSO4·5H2O in muffle furnace in the presence of CunFemO(n+1.5m) as catalyst at the same temperature.  

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

study on catalysis of cu-fe metal composite oxides to thermal decomposition behavior of bluestone

nano-cufe2o4 catalysts with different cu/fe molar ratios (cunfemo(n+1.5m)) were prepared by hydrothermal method. the thermal decomposition performance of cunfemo(n+1.5m) on cuso4 were determined with tg-dsc method to evaluate its catalytic activity and the roasted product was characterized by xrd. the results showed that cunfemo(n+1.5m) had superior catalytic properties and efficiency to cuso4 ...

متن کامل

investigation of effective parameters on the rigidity of light composite diaphragms (psscb) by fem

در این رساله با معرفی سقف های psscb متشکل از ترکیب ورق های فولادی ذوزنقه ای و تخته های سیمانی الیافی به عنوان سقف های پیش ساخته (سازگار با سیستم سازه ای قاب های فولادی سبک) به بررسی پارامترهای موثر بر صلبیت سقف، پرداخته می شود. در تحقیق حاضر ابتدا به مدل سازی دو نمونه سقف آزمایش شده، به روش اجزاء محدود با استفاده از نرم افزار تحلیلی abaqus ver 6.10 پرداخته شده است. نمونه های ساخته شده تحت اعما...

Methanol steam reforming; Effects of various metal oxides on the properties of a Cu-based catalyst

Ternary Cu/ZnO/metal oxide catalysts are prepared through the co-precipitation method under strict control of parameters like pH, calcination conditions, and precipitation temperature in a systematic manner. The metal oxides applied in this study consist of Al2O3, ZrO2, La2O3 and Ce2O3. The distinction of this work in comparison with similar research is a comprehensive investigatation of the ca...

متن کامل

Kinetic Study and Thermal Decomposition Behavior of Magnesium-Sodium Nitrate Based on Hydroxyl-Terminated Polybutadiene

This paper has been utilizing the simultaneous ThermoGravimetric analysis and Differential Scanning Calorimetry (TG–DSC) to investigate the thermal decomposition of magnesium-sodium nitrate pyrotechnic composition based HTPB resin. The thermal behaviors of different samples with various fuel-oxidizer ratio contents were determined. Decomposition kinetic was investigated by evaluating the in...

متن کامل

مروری بر اثر نانو کاتالیزگرهای بستر کربنی بر بهبود رفتار تجزیه‌ی گرمایی آمونیوم پرکلرات

Ammonium Perchlorate (AP) is one of the most important oxidizer in composite solid propellants. Therefore, synthesis and application of nanoparticles as catalyst for improving thermal decomposition of AP is an important issue in catalysis research. There are a great many nanomaterials for the thermal decomposition of AP such as nano metal particles, metal oxides, metals salts, metallic composit...

متن کامل

منابع من

با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


عنوان ژورنال

دوره 30  شماره 2

صفحات  33- 36

تاریخ انتشار 2011-06-01

با دنبال کردن یک ژورنال هنگامی که شماره جدید این ژورنال منتشر می شود به شما از طریق ایمیل اطلاع داده می شود.

میزبانی شده توسط پلتفرم ابری doprax.com

copyright © 2015-2023